Introduction UN GHS GHS CLP outline CLP Transition from DSD/DPD to CLP DSD/DPD CLP EU own Hazard Statements Classification & Harmonized classification & Requirement for SDS SDS Measures needed P23
Example of CLP label pictogram signal word product identifier precautionary statement in Multilanguage Company Identifier P24
Hazard Pictograms: code/name GHS01: Exploding bomb GHS02: Flame GHS03: Flame over circle GHS04: Gas cylinder GHS05: Corrosion GHS06: Skull and crossbones GHS07: Exclamation mark GHS08: Health hazard GHS09: Environment P25
Hazard & precautionary statements P26
Supplemental label elements/information P27
Supplemental label elements/information -cont P28
Examples of H/P statements P29
Introduction UN GHS GHS CLP outline CLP Transition from DSD/DPD to CLP DSD/DPD CLP EU own Hazard Statements Classification & Harmonized classification & Measures needed P30
Acute toxicity-oral label elements P31
Example of Label elements : skin corrosion/irritation Need solution/help! P32
Skin corrosive/irritant hazard Generic concentration limits of ingredients P33
Concentration limits Priority Generic concentration thresholds Generic concentration ti limits it minimum concentrations which trigger the classification of a mixture Generic cut-off values minimum concentrations to be taken into account for classification purposes Specific Concentration Limits(SCLs) Concentration thresholds take precedence over generic thresholds, included in Tables 3.1 and 3.2 of Annex VI to CLP and/or in the classification and labelling inventory (CLP Article 42). ) P34
Supplier s main roles and obligations VI P35
Classification P36
CLP classification (translated from DSD) Annex VI Table 3.1 List of harmonised classification & labelling of hazardous substances Minimum classification Translation table Note D : if non-stabilised form, add the words nonstabilised. Annex VI Table 3.2 The list.from Annex I to Directive 67/548/EEC P37
Criteria differences between CLP vs. DSD : Acute Toxicity-Oral LD50 5mg/kg 50mg/kg 300mg/kg 2000mg/kg For certain hazard classes, including acute toxicity and STOT repeated exposure, the DSD does not correspond directly to CLP classification. These cases is indicated by the reference * and the classification in this Annex shall be considered as a minimum classification. DSD CLP P38
Criteria differences between CLP vs. DSD : Flammable liquids DSD Criteria Criteria CLP P39
How to use harmonised classifications 1. Use harmonized classification if in Table 3.1 of Annex VI VII 2. If Notes(total nr. 24) are assigned Apply the rule Notes(24 ) ( ) 3. If not minimum classification Use the harmonized classification 4. If data are to a more severe classification Apply 5. Knowing physical state for the substance and using translation table in Annex VII, a more refined classification is obtained? Apply VII 6. Use the minimum classification P40
How to refer/use harmonized C&L 1. Refer the table of CLP Reg. AnnexVI Table3.1 CLP 2. And refer all CLP ATPs For 1. and 2., ECHA home page is available to search. ( In English) ECHA 3. Check error ( Now German errata are available) 4. To be perfect, compare with translated t CLP using AnnexVI Table3.2 (DSD)data and AnnexVII translation table VI DSD VII P41
Introduction UN GHS CLP outline Requirement for SDS Measures needed GHS CLP SDS P42
From DSD/DPD to CLP timeline P43
Transitional provisions Art.61(5) P44
Difficulties and supports P45
Thank you for your audience Contact t info. For cooperation/ further info./discussion/request please make contact with Nishimiya Kozy : nishimiya@oecc.or.jp Jun Yamaguchi : jun_yamaguchi@mbp.nifty.com P46