New OSHA Chemical Standard: What All Labs Need to Know!

Speaker 2013 Webinar Series New OSHA Chemical Standard: What All Labs Need to Know! September 19, 2013 Eric Clark, MS, Safety Officer, Los Angeles County, Downey, CA Eric Clark earned his MS in Analytical Chemistry from Oregon State University. He is also a Certified Chemical Hygiene Officer and Certified Hazardous Materials Manager. He is currently working at the Los Angeles County Public Health Laboratory as the LRN-C Level-3 Coordinator, as well as assuming the duties as the Chemical Hygiene Officer and Safety & Compliance Officer. Prior to the LRN-C program, Eric worked as a hazardous waste inspector for the State of Oregon and conducted more than 500 inspections. Objectives At the conclusion of this program, participants will be able to: Explain the changes in the hazard communication in regard to specific criteria for classification of health and physical hazards, as well as classification of mixtures. Discuss the changes that suppliers and employers are required to provide on the new standardized label. Outline the specified 16 section format for the new Safety Data Sheets (SDS). Continuing Education Credit The Association of Public Health Laboratories (APHL) is approved as a provider of continuing education programs in the clinical laboratory sciences by the ASCLS P.A.C.E. Program. Participants who successfully complete each program will be awarded 1.0 contact hours. P.A.C.E. is accepted by all licensure states except Florida. APHL is a Florida approved CE provider; each course has been approved for 1.0 contact hours for Florida Laboratory Licensees. Evaluation/Printing CE Certificate Continuing education credit is available to individuals who successfully complete the program and evaluation by March 19, 2014. 1. Go to http://www.surveymonkey.com/s/588-941-13 to complete the evaluation. 2. After you complete the evaluation, you will automatically go to the certificate site. 3. Add your information in the boxes and click on Submit. If you are requesting Florida CEU, you must submit a valid Florida license number for the certificate and for us to enter your information into CE Broker. 4. Please review your certificate. If you need to change any information, go to the bottom of the page and click on here to go back and edit. IMPORTANT: Enable printing of background images in the print (Firefox) or page setup (Internet Explorer) dialog options. 5. Certificates are available only by selecting the Print button. They will not be emailed or mailed. a. Print the certificate. b. We recommend that you also print the certificate to an adobe file and save. There is a $15 fee if you request a duplicate certificate later. Webinar certificates will no longer be saved in the Continuing Education Center (CEC). Archived Program The archived streaming video will be available within two days of the live program. Anyone from your site can view the Web archived program and/or complete the evaluation and print the CEU certificate for free. To register for the archive program go to http://www.aphl.org/courses/pages/590-941-13.aspx and use the complementary discount code 941NE in the discount box during registration. Comments, opinions, and evaluations expressed in this program do not constitute endorsement by APHL. The APHL does not authorize any program faculty to express personal opinion or evaluation as the position of APHL. The use of trade names and commercial sources is for identification only and does not imply endorsement by the program sponsors. This program is copyright protected by the speaker(s) and APHL. The material is to be used for this APHL program only. It is strictly forbidden to record the program or use any part of the material without permission from the author or APHL. Any unauthorized use of the written material or broadcasting, public performance, copying or re-recording constitutes an infringement of copyright laws. The Association of Public Health Laboratories (APHL) sponsors educational programs on critical issues in laboratory science. For more information, visit www.aphl.org/courses

New OSHA Chemical Standard: What All Labs Need to Know! Event Code: 588-941-13 Event Type: Webinar Faculty Disclosure The Association of Public Health Laboratories adheres to established standards regarding industry support of continuing education for healthcare professionals. The following disclosures of personal financial relationships with commercial interests within the last 12 months as relative to this presentation have been made by the speaker(s): Eric Clark Nothing to disclose Presented by Los Angeles County Dept. of Public Health Public Health Laboratory 1 2 Revised Standard AKA: OSHA s New Rule on the Globally Harmonized System (GHS) of Classification and Labeling of Chemicals OR Simply: GHS Labeling Standard Revised Standard Changes are happening to 29 CFR 1910.1200 All relevant GHS information can be found in The Purple Book Online key word search: GHS Purple Book 3 3 4 4 The Brief History of the Hazard Communication Rule In 1919, Alice Hamilton, MD, began working for the State of Illinois to figure out how to reduce industrial injuries and fatalities. She is generally credited with establishing the discipline of Occupational Medicine in the United States. The Brief History of the Hazard Communication Rule In 1970, the Occupational Safety and Health Administration (OSHA) was established to standardize worker safety in the US. Many states later created their own Occupational Safety agencies to include enhanced standards. 5 6

The Brief History of the Hazard Communication Rule On November 25, 1983, OSHA's Hazard Communication Standard (HCS) was first adopted in the United States with limited scope. On August 24, 1987, the HCS scope was expanded to cover all industries where employees are potentially exposed to hazardous chemicals. The Reason for the Rule Change Several countries around the world had their own labeling standards. So the US entered into a United Nations negotiation to help create a Globally Harmonized System (GHS). To be fully implemented by June 1, 2016. 7 8 Three Changes Occurred Hazard classification: The definitions of hazard have been changed to provide specific criteria for classification of health and physical hazards, as well as classification of mixtures. Labels: Suppliers and employers are required to provide a standardized label. Safety Data Sheets (SDS): Will now have a specified 16-section format. Can include mixtures and organisms. [Not MSDS anymore.] The Transition Timeline for Suppliers June 1, 2015: Comply with all modified provisions of the final rule, but can still ship old stock with old labels until December 1, 2015: All manufacturer labeling must comply with GHS standards. 9 10 The Transition Timeline for Employers December 1, 2013: Train employees on the new label elements and safety data sheet (SDS) format. What suppliers labels must have June 1, 2016: Update alternative workplace labeling and hazard communication program as necessary, and provide additional employee training for newly identified physical or health hazards. 11 12

Product Identifier Signal Word 13 14 A couple of words about Signal Words Pictogram There are only two signal words used in this section: Danger" and Warning." "Danger" is used for the more severe hazards, Warning" is used for the less severe. 15 16 Pictograms must have a black symbol on a white background with a red diamond frame. Gasses Under Pressure Gasses Under Pressure 17 18

Pictograms must have a black symbol on a white background with a red diamond frame. Pictograms must have a black symbol on a white background with a red diamond frame. Gasses Under Pressure Gasses Under Pressure Ketchup 19 20 Pictograms must have a black symbol on a white background with a red diamond frame. Pictograms must have a black symbol on a white background with a red diamond frame. Not GHS compliant pictograms Gasses Under Pressure Ketchup Mustard Gasses Under Pressure Ketchup Mustard 21 22 Pictograms must have a black symbol on a white background with a red diamond frame. Not GHS compliant pictograms Oxidizer Gasses Under Pressure X Ketchup X Mustard 23 24

Flammable Self Reactive Pyrophoric Self-Heating Emits Flammable Gas Organic Peroxides Explosive Self Reactive Organic Peroxides 25 26 Careful about storing Acute Toxicity (severe) based on the Pictogram Acute Toxicity (severe) Just because some chemicals might have the same pictogram, does not necessarily mean they can be stored together. E.g., Sulfuric Acid and Cyanide Salts both use the same pictogram, Acute Toxicity (severe). 27 28 Corrosive And be careful about storing Corrosives based on the Pictogram Corrosive for ph means o Acid, LOW ph (< 2.0) and o Base, HIGH ph (>12.5) Acids and Bases both use the same Pictogram. Be sure to let everybody know about these kinds of incompatibilities. 29 30

Carcinogen Respiratory Sensitizer Reproductive Toxicity Target Organ Toxicity Irritant Acute Toxicity Dermal Sensitizer Narcotic Effects 31 32 Hazard Statement *Environmental Toxicity *Not required as a labeling pictogram in the US under the new Rules. OSHA enforces worker safety laws, not environmental protection laws. 33 34 Precautionary Statement Supplier name, address, phone 35 36

Hatched Border (Canada) Safety Data Sheets They all must use the 16-point standard 37 38 Safety Data Sheets Section 1. Identification Section 2. Hazard(s) identification Section 3. Composition/information on ingredients Section 4. First-Aid measures Section 5. Fire-fighting measures Section 6. Accidental release measures Section 7. Handling and storage Section 8. Exposure controls/personal protection Section 9. Physical and chemical properties Section 10. Stability and reactivity Section 11. Toxicological information Section 12. Ecological information Section 13. Disposal considerations Section 14. Transport information Section 15. Regulatory information Section 16. Other information, including date of preparation or last revision Section 1. Identification (copied/pasted below from SDS) Safety Data Sheets 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Sulfuric acid Product Number : 435589 Brand : Sigma-Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street, SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For both supplier and manufacturer): (314) 776-6555 Preparation Information : Sigma-Aldrich Corporation Product Safety - Americas Region 1-800-521-8956 39 40 Section 2. Hazard(s) Identification (partially copied/pasted below from SDS) 2. HAZARDS IDENTIFICATION Pictogram Signal word: Danger Safety Data Sheets Hazard statement(s): H314 Causes severe skin burns and eye damage. Harmful to aquatic life. Precautionary statement(s): Wear protective gloves/ protective clothing/ eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Labeling Requirements for Relabeling Workplace Containers Some examples of workplace situations where chemicals may be transferred from supplier containers include: containers for laboratory testing, storage vessels, piping or process reaction systems, temporary containers. NFPA Rating: Health hazard: 3; Fire: 0; Reactivity Hazard: 2; Special hazard: W 41 42

43 Labeling Requirements for Relabeling Workplace Containers Alternative labeling systems are permitted such as National Fire Protection Association (NFPA) 704 Hazard Rating. Hazardous Material Information System (HMIS). Equivalent labeling as determined by Competent Authority. 44 Workplace labels when chemicals are transferred to other containers Each hazard class is ranked: Severe = 4; Serious = 3; Moderate = 2; Slight = 1; Minimal = 0 Labeling Requirements for Relabeling Workplace Containers A word about NFPA Diamonds: they re designed for firefighters NFPA Diamond for Sulfuric Acid NFPA Diamond for Acetone NFPA label Firefighters rule of thumb: If the numbers for a room add up to 7, don t go in there if you don t have to. NFPA Diamond for door to a room containing Sulfuric Acid and Acetone 45 46 Labeling Requirements for Relabeling Workplace Containers No workplace label is ok if the controlled product is HMIS label Controlled & used only by the worker filling the container, and used up during the shift. 47 48

Questions Eric Clark, MS, CCHO, CHMM Los Angeles County Public Health Laboratory 562-658-1486 erclark@ph.lacounty.gov 49

Name Quiz Date Score: Training Date: Measurement of Understanding for the Globally Harmonized System. For questions 1 7, select the one best answer. (7 points) (1) All relevant information regarding the workplace rules can be found in the United Nations Guide to The Globally Harmonized System of Classification and Labeling of Chemicals. This publication is informally known as a. Redbook b. The Orange Book c. The Yellow Pages d. The Purple Book (2) The GHS-compliant Safety Data Sheet (SDS) has this many defined standardized sections: a. Four b. Eight c. Sixteen d. Thirty-two (3) The National Fire Prevention Association (NFPA) symbol looks like a a. Triangle b. Square c. Diamond d. Rectangle (4) The Hazardous Materials Information System (HMIS) symbol looks like a a. Triangle b. Square c. Diamond d. Rectangle (5) The numbers on the NFPA and HMIS symbols mean a. Severe = 4; Serious = 3; Moderate = 2; Slight = 1; Minimal = 0 b. Severe = 5; Serious = 4; Moderate = 3; Slight = 2; Minimal = 1 (6) Under GHS rules, when secondary laboratory containers must be re-labeled, they may use which of the following schemes? a. National Fire Prevention Association (NFPA) b. Hazardous Materials Information System (HMIS) c. Any system deemed appropriate by a recognized Competent Authority d. Any of the above (7) Under GHS rules, under what circumstances is it permissible for a controlled product to be held in an un-labeled laboratory container? a. When the controlled product is used only by the worker filling the container. b. When the controlled product is used up during the shift. c. Only when both of the above conditions (a & b) are met. d. It is never permitted.

(8) Match up the pictogram number above with the correct description below, as shown in the example. (8 points)

(9) Circle the section of the label above and match it up with the number for the correct description below, as shown in the example. (5 points)

OSHA 3658-06 2013 (10-UP)

OSHA 3658-06 2013 (10-UP)